对西安市电子二路(XZ)和长安区郭杜镇(XCA)两个样点2012年1月至2013年12月连续两年的大气降尘进行详细系统环境磁学实验分析。结果表明:西安市大气降尘中磁性矿物含量相对较高,主要的磁性矿物为多畴和假单畴的低矫顽力亚铁磁性矿物,并伴有少量的赤铁矿等高矫顽力的硬磁性矿物,磁畴主要由粗颗粒的MD(多畴)和PSD(准单畴)组成。XZ样点大气降尘的磁性浓度和磁性矿物的粒径大于XCA样点,表明城市不同功能区污染源类型存在差异。西安市大气降尘磁性矿物含量表现出明显的季节变化的特征,5-8月(夏季)磁性矿物的浓度明显较低,10月到次年的1月(冬季)是磁性矿物浓度最大的时期,这主要与采暖期排放源的变化有关,另外,西安市特殊的地形和气象因素对大气粉尘的扩散产生重要的影响,导致冬季粉尘的富集。
Environmental magnetic measurements were carried out on the dustfall samples from Xi'an. These samples were collected in every month from January 2012 to December 2013 at XZ and XCA sites. The magnetic parameters (χlf, χARM, SIRM, FORC diagram and magnetic hysteresis parameters) indicate a relatively high concentration of ferrimagnetic minerals in Xi'an, dominated by multiple domain (MD) and pseudo-single domain (PSD) ferrimagnetic minerals. The concentration of magnetic minerals in XZ site is higher than those in XCA site, suggesting the different pollution sources in different functional district of Xi'an. The concentration of magnetic minerals has significant changes according to the seasons in each year, and the values rise from October to January of next year, and decrease in summer, which mainly not only come from the pollution of coal-burning, but also are influenced by the special topography and meteorological conditions.
[1] Fergusson J E.Dust in the environment:elemental composition and sources[M]//Science of Global Change.American Chemical Society, 1992:117-133.
[2] Han Y M, Du P X, Cao J J, et al.Multivariate analysis of heavy metal contamination in urban dusts of Xi'an, Central China[J].Science of the Total Environment, 2006, 355(17):176-186.
[3] Al-Chalabi A S, Hawker D.Response of vehicular lead to the presence of street dust in the atmospheric environment of major roads[J].Science of the Total Environment, 1997, 206(11):195-202.
[4] 闫海涛, 胡守云, 朱育新.磁学方法在环境污染研究中的应用[J].地球科学进展, 2004, 19(5):231-236.
[5] 张春霞, 黄宝春.环境磁学在城市环境污染监测中的应用和进展[J].地球物理学进展, 2005, 20(5):705-711.
[6] Durža O.Heavy metals contamination and magnetic susceptibility in soil around metallurgical plant[J].Physical Chemistry Earth, 1999, 24(6):541-543.
[7] Jeleńska M, Hasso-Agopsowicz A, Kopcewicz B, et al.Magnetic properties of the profiles of polluted and non-polluted soils:a case study from Ukraine[J].Geophysical Journal International, 2004, 159(11):104-116.
[8] Hay K L, Dearing J A, Baban S M J, et al.A preliminary attempt to identify atmospherically derived pollution particles in English topsoils from magnetic susceptibility measurements[J].Physical Chemistry Earth, 1997, 22(5):207-210.
[9] Stone E, Schauer J, Quraishi TA, et al.Chemical characterization and source apportionment of fine and coarse particulate matter in Lahore, Pakistan[J].Atmospheric Environment, 2010, 44(8):1062-1070.
[10] Blundell A, Dearing J A, Boyle J F, et al.Controlling factors for the spatial variability of soil magnetic susceptibility across England and Wales[J].Earth-Science Review, 2009, 95(7):158-188.
[11] Harrison R M, Smith D J T, Piou C A, et al.Comparative receptor modelling study of airborne particulate pollutants in Birmingham (UK), Coimbra (Portugal) and Lahore (Pakistan)[J].Atmospheric Environment, 1997, 31(11):3309-3321.
[12] Blundell A, Hannam J A, Dearing J A, et al.Detecting atmospheric pollution in surface soils using magnetic measurements:A reappraisal using an England and Wales database[J].Environmental Pollution, 2009, 157(12):2878-2890.
[13] Canbay M, Aydin A, Kurtulus C.Magnetic susceptibility and heavy-metal contamination in topsoils along the Izmit Gulf coastal area and IZAYTAS (Turkey)[J].Journal Applied Geophysical, 2010, 70(6):46-57.
[14] 乔庆庆, 张春霞, 李静, 等.北京市朝阳区大气降尘磁学特征及对空气污染物浓度的指示[J].地球物理学报, 2011, 54(1):151-162.
[15] 王博, 许淑婧, 夏敦胜, 等.塔里木盆地现代天然降尘磁性特征时空对比研究[J].中国沙漠, 2013, 33(3):840-849.
[16] 田世丽, 夏敦胜, 余晔, 等.北京市大兴区大气降尘环境磁学特征及其环境意义[J].中国沙漠, 2013, 33(3):832-839.
[17] Harrison R M, Yin J X.Particulate matter in the atmosphere:Which particle properties are important for its effects on health?[J].Science of the Total Environment, 2000, 249(13):85-101.
[18] Xia D S, Yang L P, Ma J Y, et al.Magnetic characteristics of dustfall in urban area of north China and its environmental significance[J].Science in China:Series D, 2007, 50(12):1724-1732.
[19] Karimi R, Ayoubi S, Jalalian A, et al.Relationships between magnetic susceptibility and heavy metals in urban topsoils in the arid region of Isfahan, central Iran[J].Journal Applied Geophysical, 2011, 74(3):1-7.
[20] Wei B G, Yang L S.A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China[J].Microchemical Journal, 2010, 94(13):99-107.
[21] 乔庆庆, 黄宝春, 张春霞, 等.华北地区大气降尘和地表土壤磁学特征及污染来源[J].科学通报, 2014, 59(18):1748-1760.
[22] Dunlop D J, zdemir .Rock Magnetism:Fundamentals and Frontiers[M].New York, USA:Cambridge University Press, 1997.
[23] Dearing J.Environmental Magnetic Susceptibility:Using the Bartington MS2 System[M].Kenilworth, UK:Chi Publishing, 1994.
[24] Evans M E, Heller F.Environmental Magnetism:Principles and Applications of Environmagnetics[M].New York, USA:Academic Press, 2003:68-77.
[25] Liu Q S, Roberts A P, Larrasoa a J C, et al.Environmental magnetism:principles and applications[J].Reviews of Geophysics, 2012, 50(4):1-50.
[26] Maher B A, Thompson R.Quaternary Climates, Environments and Magnetism[M].Cambridge, UK:Cambridge University Press, 1999:49-53.
[27] Thompson R, Oldfield F.Environmental Magnetism[M].London, UK:Allen and Uniwin, 1986:1-227.
[28] Dankers P.Relationship between median destructive field and remanent coercive force for dispersed naturl magnetite, titanomagnetite and hematite[J].Journal of Geophysical Research, 1981, 64(2):44-461.
[29] Muxworthy A R, King J G, Heslop D.Assessing the ability of first-order reversal curve (FORC) diagrams to unravel complex magnetic signals[J].Journal of Geophysical Research, 2005, 110(12):1-11.
[30] Roberts A P, Pike C P, Verosub K L.First-order reversal curve diagrams:a new tool for characterizing the magnetic properties of natural sample s[J].Journal of Geophysical Research, 2000, 105(8):28461-28475.
[31] Pike C R, Roberts A P, Dekkers M J, et al.An investigation of multi-domain hysteresis mechanisms using FORC diagrams[J].Physical Earth Plannetery International, 2001, 126(11):11-25.
[32] 王丽, 夏敦胜, 余晔, 等.北疆地区城市大气降尘磁学特征及其环境意义[J].中国沙漠, 2010, 30(3):699-705.